Removal of Reactive Blue 13 Using Modified Cellulosic Material Based on Rice Husks

Authors

  • Paunka Vassileva Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences
  • Ivan Uzunov Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences
  • Dimitrinka Voykova Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences
  • Ignat Ignatov Scientific Research Center of Medical Biophysics (SRCMB), Bulgaria

DOI:

https://doi.org/10.7546/CRABS.2024.12.03

Keywords:

Reactive Blue 13, rice husks, adsorption, cellulose

Abstract

The present study deals with the removal efficiency regarding Reactive Blue 13 (RB) of a cationized cellulosic adsorbent prepared from agricultural waste. The rice husks were used as a raw material to extract and separate the cellulose by alkali and bleaching treatment. The cellulosic material was modified with N, N-dimethyl-1-octadecylamine to prepare a cationized adsorbent. The adsorption process was scrutinized across multiple parameters influencing dye removal and was well described by pseudo-second-order and Langmuir models predicting chemically rate-controlled monolayer adsorption. Thermodynamic studies show that the adsorption of RB is spontaneous and endothermic. It was established that the new cationized cellulosic material could serve as an effective adsorbent for the removal of RB from aqueous media.

Author Biographies

Paunka Vassileva, Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences

Mailing Address:
Institute of General and Inorganic Chemistry,
Bulgarian Academy of Sciences
Akad. G. Bonchev St, Bl. 11, 1113 Sofia, Bulgaria

E-mail: pnovachka@svr.igic.bas.bg

Ivan Uzunov, Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences

Mailing Address:
Institute of General and Inorganic Chemistry,
Bulgarian Academy of Sciences
Akad. G. Bonchev St, Bl. 11, 1113 Sofia, Bulgaria

E-mail: uzunov_iv@svr.igic.bas.bg

Dimitrinka Voykova, Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences

Mailing Address:
Institute of General and Inorganic Chemistry,
Bulgarian Academy of Sciences
Akad. G. Bonchev St, Bl. 11, 1113 Sofia, Bulgaria

E-mail: dimitrinka@svr.igic.bas.bg

Ignat Ignatov, Scientific Research Center of Medical Biophysics (SRCMB), Bulgaria

Mailing Address:
Scientific Research Center of Medical Biophysics (SRCMB),
32 Nikolay Kopernik St, 1111 Sofia, Bulgaria

E-mail: mbioph@abv.bg

Downloads

Published

25-12-2024

How to Cite

[1]
P. Vassileva, I. Uzunov, D. Voykova, and I. Ignatov, “Removal of Reactive Blue 13 Using Modified Cellulosic Material Based on Rice Husks”, C. R. Acad. Bulg. Sci., vol. 77, no. 12, pp. 1757–1766, Dec. 2024.

Issue

Section

Chemistry